Efficient benzylic and aliphatic C-H oxidation with selectivity for methylenic sites catalyzed by a bioinspired manganese complex.
نویسندگان
چکیده
A benzimidazole-based nonheme manganese complex efficiently catalyzes benzylic, aliphatic C-H as well as tertiary C-H oxidation with hydrogen peroxide as the oxidant in the presence of acetic acid as additive. (18)O labeling experiments suggest the reaction may proceed via a high-valent manganese-oxo intermediate.
منابع مشابه
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ورودعنوان ژورنال:
- Organic letters
دوره 16 4 شماره
صفحات -
تاریخ انتشار 2014